Group 2, Alkaline Earth Metals

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Trends

Very quickly we shall go over the trends in properties of Group 2 elements using the below table.

Atomic Radius The atomic radii increase down the group. This is because new electron shells are added to the atom, making it larger.
1stionisation energy The first ionization energies decrease down the group, this is because there are more electron shielding and a greater distance of the outermost electrons from the nucleus.
Electronegativity The electronegativity decrease down the group because the nuclear charge has less effect on the outermost electrons, so the atom will give them up more readily.

Reactions in Water

When added to water, the first alkaline earth metal, (Beryllium), is totally nonreactive, and doesn't even react with steam. Then as you move down the group, the reactions become increasingly vigorous.

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As an example, the following reaction takes place between magnesium and water, an alkali earth metal hydroxide and hydrogen gas is produced. Magnesium can be substituted for any Group 2 metal, however.

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Mg(s) + H2O(l) ® Mg(OH)2 (aq) + H2

When magnesium is reacted with steam, it is even more vigorous, and instead of a hydroxide, an oxide is produced as well as hydrogen gas.

Mg(s) + H2O(g) ® MgO(s) + H2 (g)

Solubility

Here we shall look at the solubilities of the hydroxides and sulfates of Group 2 metals.

Solubility is the maximum amount a substance will dissolve in a given solvent. It is measured in either, grams or moles per 100g of water.

The trends of solubility for hydroxides and sulfates are as follows:

solubility trends of group 2 hydroxides and sulphates

Magnesium hydroxide (Mg(OH)2) is said to be sparingly soluble because it does not dissolve in very well and Be(OH)2 and BaSO4 are insoluble.

The chemical test for a sulphate is to add Barium Chloride. If positive, the solution will go milky. This means the precipitate barium sulfate has been formed; which, as you can see from the solubility table above, this is insoluble.

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Beryllium is Different

Beryllium differs from its brothers and sisters in Group 2 in that it usually forms covalent bonds, but unlike other covalent molecules, it is soluble in organic solvents and a poor conductor when molten. Another strange feature is that it is amphoteric. This means it has the properties of both an acid and a base. The two reactions below show this:

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Be(OH)2 (s) + H2SO4 (aq) ® BeS4 (aq) + 2H2O(l)

Be(OH)2 (s) + 2NaOH(aq) ® Na2Be(OH)4 (aq)

Questions and Answers

Please help me to understand the solubility trend of group 2 salt trend?

Solubility is the maximum amount a substance will dissolve in a given solvent. It is measured in either, grams or moles per 100g of water. As salt is a sulfate, the solubility differs depending on the type of salt and whether the salt is hydrated or not. Magnesium sulfate and calcium sulfate (both salts) are considered insoluble unless they are hydrated.

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Categories : Fundamental

Recent edits by: SarMal, Jen Moreau, Taylor (ScienceAid Editor)

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